Microsoft have released a guide for configuring and applying Group Policy in Microsoft Office 2010.
The guide states that " it provides a guide is the IT administrator who plans to use Group Policy to configure and enforce settings for Microsoft Office 2010 applications." In addition to providing an insight into Group Policy for Office 2010, the guide also provides an insight into how Group Policy functions and is applied at a Windows level.
I have had a quick read through the guide and it makes interesting reading.

October 21, 2010 
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[...] Active Directory aficionado Mark Parris recently posted about the Office 2010 Group Policies on his blog. I personally enjoyed the document and anyone who will deploy Office 2010 soon should definitely [...]